Copolymerization. VI. Reprecipitation of Copolymers of Vinylchloride with Methyl Acrylate.
نویسندگان
چکیده
منابع مشابه
Mechanistic Studies of the Palladium-Catalyzed Copolymerization of Ethylene and R-Olefins with Methyl Acrylate
Mechanistic aspects of palladium-catalyzed insertion copolymerizations of ethylene and R-olefins with methyl acrylate to give high molar mass polymers are described. Complexes [(N∧N)Pd(CH2)3C(O)OMe]BAr′4 (2) or [(N∧N)Pd(CH3)(L)]BAr′4 (1: L ) OEt2; 3: L t NCMe; 4: L t NCAr′) (N∧N ≡ ArNdC(R)-C(R)dNAr, e.g., Ar t 2,6-C6H3(i-Pr)2, R t H (a), Me (b); Ar′ t 3,5-C6H3(CF3)2) with bulky substituted R-di...
متن کاملPhotodegradation of Methacrylate/acrylate Copolymers
Although the effects of u.v. radiation on poly(methyl methacrylate) and poly(methyl acrylate) are superficially different, nevertheless there are obvious fundamental similarities and this copolymer system was chosen for study in order to observe the influence of one type of chain unit on the degradation reactions of the other. Rates of chain scission and crosslinking were measured at room tempe...
متن کاملCalorimetric study of block-copolymers of poly(n-butyl acrylate) and gradient poly(n-butyl acrylate-co-methyl methacrylate)
The nanophase separation in diblock and triblock copolymers consisting of immiscible poly(n butyl acrylate) (block A) and gradient copolymers of methyl methacrylate (MMA) and n butyl acrylate (n BA) (block M/A) were investigated by means of their heat capacity, Cp, as a function of the composition of the blocks M/A and temperature. In all copolymers studied, both blocks are represented by their...
متن کاملGraft copolymerization of methyl acrylate on chitosan: Initiated by ceric ammonium nitrate as the initiator-characterization and antimicrobial activity
Methyl acrylate was grafted onto chitosan by using the ceric ammonium nitrate as the initiator. The effect of initiator concentration, monomer concentration, time & temperature on % G and % E were studied. The grafted samples were characterized using FTIR, SEM, TGA methods. Evidence of grafting was confirmed by FTIR spectroscopy. The morphology evaluated by SEM. The thermal analysis indicated t...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: The Journal of the Society of Chemical Industry, Japan
سال: 1954
ISSN: 0023-2734,2185-0860
DOI: 10.1246/nikkashi1898.57.678